American Journal of Environmental Sciences

BEHAVIOR OF THE NON-SELECTIVE HERBICIDE GLYPHOSATE IN AGRICULTURAL SOIL

Abdul Jabbar Al-Rajab and Othman M. Hakami

DOI : 10.3844/ajessp.2014.94.101

American Journal of Environmental Sciences

Volume 10, Issue 2

Pages 94-101

Abstract

Glyphosate [N-phosphonomethyl]glycine is a systematic, non-selective, organophosphorus herbicide used worldwide in agriculture and industrial zones. Following its application, residues of glyphosate can threaten soil or aquatic organisms in adjacent water. In this study, we followed the degradation, stabilization, remobilization and leaching of 14C-glyphosate in three agricultural soils in laboratory incubations and in lysimeters under field conditions. Glyphosate degradation was relatively rapid with a half-life of 14.5 days in the silt clay loam soil incubated at 20°C. Glyphosate’s degradation product, Aminomethylphosphonic Acid (AMPA), represented more than 85% of residues after 80 days of laboratory incubation. Leaching of glyphosate in lysimeters of three different investigated soils under outdoor conditions was very slow, less than 1% of the initial applied amount has been detected in the leachates after 100 days of experimentation. Glyphosate rapidly formed non-extractable residues after treatment. In summary, glyphosate was removed from soil very rapidly and its leaching seems to be very slow regardless the type of treated soil. On the other hand, the contamination risk of groundwater with its metabolite AMPA at long term is probably due to the release of the non-extractable residues.

Copyright

© 2014 Abdul Jabbar Al-Rajab and Othman M. Hakami. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.